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21.
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超级铝热剂的制备、表征及其燃烧催化作用 总被引:3,自引:0,他引:3
用纳米铝粉和纳米氧化铅、纳米氧化铜和纳米三氧化二铋为原料,采用超声分散复合的方法,制备了纳米超级铝热剂Al/PbO、Al/CuO和Al/Bi2O3。采用X射线粉末衍射(XRD)、扫描电镜及能谱分析(SEM-EDS)和红外光谱(IR)对原料和产物的物相、组成、形貌和结构进行分析表征;运用差示扫描量热仪(DSC)评估三种超级铝热剂与双基推进剂主要组分的相容性;研究了3种超级铝热剂对双基推进剂燃烧性能的影响。结果表明,Al/PbO、Al/CuO和Al/Bi2O3与推进剂主要组分硝化棉(NC)、硝化棉/硝化甘油(NC/NG)混合物和吉纳(DINA)的相容性均良好,而与黑索今(RDX)和1,3-二甲基-1,3-二苯基脲(C2)相对较为敏感;含三种纳米超级铝热剂的双基推进剂表现出优异的燃烧性能。 相似文献
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一种薄板弯曲问题的四边形位移单元 总被引:32,自引:0,他引:32
本文基于修正势能泛函,引入广义协调的概念,导出了一种具有12个自由度的薄板弯曲四边形位移单元LGC—Q12,这种单元协调性好,列式简单,计算精度高。并且能近似地通过分片检验。 相似文献
25.
Jen‐Taut Yeh Chi‐Hui Tsou Wei Lu Ya‐Ming Li Han Wen Xiao Chi‐Yuan Huang Kan‐Nan Chen Chin‐San Wu Wan‐Lan Chai 《Journal of Polymer Science.Polymer Physics》2010,48(9):913-920
Fourier transform infrared and nuclear magnetic resonance results suggest that the carboxylic acid groups of poly(lactic acid) (PLA) molecules react with the hydroxyl groups of FePol (FP) molecules during the melt‐blending of PLAxFPy specimens. Differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) experiments of PLA and PLA/FP specimens suggest that only small amounts of poor PLA and/or FP crystals are present in their corresponding melt crystallized specimens. In fact, the percentage crystallinity, peak melting temperature, and onset re‐crystallization temperature values of PLA/FP specimens reduce gradually as their FP contents increase. However, the glass transition temperatures of PLA molecules found by DSC and DMA reduce to a minimum value as the FP contents of PLAxFPy specimens reach 6 wt %. Further DMA and morphological analysis of PLA/FP specimens reveal that FP molecules are compatible with PLA molecules at FP contents equal to or less than 6 wt %, as no distinguished phase‐separated FP droplets and tan δ transitions were found on fracture surfaces and tan δ curves of PLA/FP specimens, respectively. In contrast to PLA, the FP specimen exhibits highly deformable and tearing properties. After blending proper amounts of FP in PLA, the inherent brittle deformation and poor tearing behavior of PLA were successfully improved. Possible reasons accounting for these interesting crystallization, compatible and tearing properties of PLA/FP specimens are proposed. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 913–920, 2010 相似文献
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The determining equations for the nonclassical symmetry reductions of nonlinear partial differential equations with arbitrary order can be obtained by requiring the compatibility between the original equations and the invariant surface conditions. The (2+1)-dimensional shallow water wave equation,
Boussinesq equation, and the dispersive wave equations in shallow water serve as examples illustrating how compatibility leads quickly and easily to the determining equations for their nonclassical symmetries. 相似文献
28.
由壳聚糖(CS)、聚乙烯醇(PVA)和三聚磷酸钠(TPP)制备了壳聚糖/聚乙烯醇/三聚磷酸钠三元复
合微球,探讨了体系中壳聚糖含量对复合微球的影响,以及离子种类及浓度和pH值对复合微球溶胀度的影
响。采用XRD、FTIR和SEM等测试技术对微球的组分、结构和形貌进行了表征。结果表明,CS和PVA具有良好的相容性,随着CS含量的增加,PVA的结晶性逐渐降低,复合微球的粒径约为400~950 μm,表面较为粗糙;随着CS添加量的增加,凝胶平衡溶胀度先增大再减小,CS/PVA/TPP复合微球在pH值为3~8的溶胀度最大,且在同一种溶液中,随着离子浓度的增加,其溶胀度明显降低;复合微球具有溶胀 收缩可逆性,显示CS/PVA/TPP复合微球是pH/离子敏感型凝胶,可为药物缓释系统提供实验和理论依据。 相似文献
29.
陈海珍 《宁波大学学报(理工版)》2010,23(1):123-127
通过3种不同的表面活性剂对纳米TiO2进行了表面修饰,并制备了纳米TiO2/PET复合材料.使用透射电镜、傅立叶红外光谱仪、DSC差热分析方法研究了表面活性刹对纳米TiO2分散性和相溶性以及对PET复合材料的化学结构和热性能的影响.结果表明:钛酸丁酯修饰纳米粒子与PET相溶性较好;纳米TiO2表面在表面活性剂的影响下可能形成了Ti-OCOR键合,从而对纳米TiO2/PET复合材料热性能影响较大. 相似文献
30.
In this paper we develop models within a thermodynamic standpoint that are very similar in form to the classical Maxwell and Oldroyd-B models but differ from them in one important aspect, the manner in which they unload instantaneously from the deformed configuration. As long as the response is not instantaneous, the models that are derived cannot be differentiated from the Maxwell and Oldroyd-B models, respectively. The models can be viewed within the context of materials whose natural configuration evolves, the evolution being determined by the maximization of the rate of entropy production of the material. However, the underpinnings to develop the model are quite different from an earlier development by Rajagopal and Srinivasa [8] in that while the total response of the viscoelastic fluid satisfies the constraint of an incompressible material, the energy storage mechanism associated with the elastic response is allowed to be that for a compressible elastic solid and the dissipative mechanism associated with the viscous response allowed to be that for a compressible fluid, the total deformation however being isochoric. The analysis calls for a careful evaluation of firmly held customs in viscoelasticity wherein it is assumed that it is possible to subject a material to a purely instantaneous elastic response without any dissipation whatsoever. Finally, while the model developed by Rajagopal and Srinivasa [8] arises from the linearization of the non-linear elastic response that they chose and leads to a model wherein the instantaneous elastic response is isochoric, here we develop the model within the context of a different non-linear elastic response that need not be linearized but the instantaneous elastic response not necessarily being isochoric. 相似文献